If you don't have the scheduling feature, you can still setup Punch Limiting for your employees. To set this feature up, you'll want to start by visiting Settings --> Punch Limiting and select +Add a New Punch Limiting Rule. You can create as many rules as you'd like, but employees can only be assigned one rule at a time.
Setting up the rule itself is quite simple. First enter a rule name, then specify the timeframe an employee is allowed to punch in or out. If you'd like to restrict an employee from punching any time on a particular day simply enter the same start and end time.
Once you've set the range per day check the Active box, assigned the appropriate employees, and click Save.