Go to Employees --> View. If time off is enabled (Settings --> Time Off to enable it) you will see a Time Off button for the employee. Click the Time Off button and you'll be taken to the Time Off section where you can view Time Off types, balances, and transactions. You can also add entries to the employee by selecting +Add Time Off Accrual Entry.
If you would like to download the transactions, click on "View" next to the type. You then have downloadable options for PDF & CSV.